{"id":30608,"date":"2018-07-24T14:03:32","date_gmt":"2018-07-24T12:03:32","guid":{"rendered":"https:\/\/aktuelles.uni-frankfurt.de\/?p=30608"},"modified":"2023-02-22T19:56:17","modified_gmt":"2023-02-22T18:56:17","slug":"made-to-measure-silicon-building-blocks","status":"publish","type":"post","link":"https:\/\/aktuelles.uni-frankfurt.de\/en\/english\/made-to-measure-silicon-building-blocks\/","title":{"rendered":"Made-to-measure silicon building blocks"},"content":{"rendered":"<p><em><strong>Range of applications for silicones on the increase thanks to modular, combinable building blocks.<\/strong><\/em><\/p>\n<p>Silicones are synthetic materials used in a broad range of applications. Thanks to the stability of the silicon-oxygen bond, they are resistant to chemicals and environmental influences and also harmless from a physiological point of view. As a result, silicones contribute to making everyday life easier in almost all areas. In the\u00a0<em>Journal of the American Chemical Society,\u00a0<\/em>chemists at Goethe University Frankfurt have now described a new way to produce long-awaited silicon building blocks in a simple and efficient way.<\/p>\n<p>The broad spectrum of applications for silicones ranges from medical implants and cosmetics to hydraulic oils and sealants to corrosion protection \u2013 an important topic in view of global corrosion damage to the tune of about US$ 3.3 trillion per year. To optimize silicon-based synthetic materials for specific applications, made-to-measure chlorosilane building blocks are required in order to produce and crosslink the long-chain polymers. This influences, for example, the material\u2019s viscosity and flow properties. Completely new challenges are emerging in the area of 3D printing, with the aid of which products such as individualized running shoes can be manufactured.<\/p>\n<p>Since 1940, the M\u00fcller-Rochow Direct Process has formed the backbone of the silicone industry. In this process, elementary silicon is converted with methyl chloride into methylchlorosilanes at high temperatures and pressures in the presence of a copper catalyst. The working group led by Professor Matthias Wagner at the Institute of Inorganic and Analytical Chemistry of Goethe University Frankfurt has now developed a complementary process that has several advantages over the Direct Process: It uses hexachlorodisilane and chlorinated hydrocarbons as starting materials. \u201cHexachlorodisilane is already mass-produced for the semiconductor industry and the perchlorethylene (PER) we use particularly frequently is a non-flammable liquid which is so inexpensive that it\u2019s used worldwide as a solvent for dry cleaning,\u201d says Matthias Wagner. In addition, the process runs at room temperature and under normal pressure. To activate it, just a small concentration of chloride ions is needed in place of a catalyst.<\/p>\n<p>\u201cOur process produces highly functionalized organochlorosilanes that are ideal crosslinkers. In addition, their special structure offers excellent possibilities to adjust the mechanical flexibility of the silicon chains as desired,\u201d explains co-inventor Isabelle Georg, whose doctoral dissertation is being sponsored by the Evonik Foundation. Julian Teichmann was also involved in the project. He confirms that above all the close collaboration between Goethe University and Evonik had a tremendous influence on his training: \u201cRegular discussion of our results with Evonik\u2019s industrial chemists opened my eyes from the beginning to economic constraints and ecological requirements. It was fascinating to follow the path from our discoveries in the lab via the patenting procedures to realization on a technical scale in practice.\u201d<\/p>\n<p>The chemists in Frankfurt believe that their monomers\u2019 special potential lies in the fact that they contain not only silicon-chlorine bonds but also carbon-carbon multiple bonds. The purpose of the former is to construct the inorganic silicon-oxygen chains; the latter can be linked to form organic polymers. This unique combination permits new routes to inorganic-organic hybrid materials.<\/p>\n<p>[dt_call_to_action content_size=&#8220;small&#8220; background=&#8220;fancy&#8220; line=&#8220;true&#8220; style=&#8220;1&#8243; animation=&#8220;fadeIn&#8220;]<\/p>\n<p><strong>Publication:<\/strong> I. Georg et al: Exhaustively Trichlorosilylated C1 and C2 Building Blocks: Beyond the M\u00fcller-Rochow Direct Process, in: J. Am. Chem. Soc. 2018, DOI: 10.1021\/jacs.8b05950<\/p>\n<p>[\/dt_call_to_action]<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Range of applications for silicones on the increase thanks to modular, combinable building blocks. Silicones are synthetic materials used in a broad range of applications. Thanks to the stability of [&hellip;]<\/p>\n","protected":false},"author":8,"featured_media":30604,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_eb_attr":"","_price":"","_stock":"","_tribe_ticket_header":"","_tribe_default_ticket_provider":"","_ticket_start_date":"","_ticket_end_date":"","_tribe_ticket_show_description":"","_tribe_ticket_show_not_going":false,"_tribe_ticket_use_global_stock":"","_tribe_ticket_global_stock_level":"","_global_stock_mode":"","_global_stock_cap":"","_tribe_rsvp_for_event":"","_tribe_ticket_going_count":"","_tribe_ticket_not_going_count":"","_tribe_tickets_list":"[]","_tribe_ticket_has_attendee_info_fields":false,"footnotes":""},"categories":[126,261,150],"tags":[244],"post_folder":[],"class_list":["post-30608","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-english","category-in-brief","category-news-in-brief","tag-chemistry"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.9 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Made-to-measure silicon building blocks | Aktuelles aus der Goethe-Universit\u00e4t Frankfurt<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/aktuelles.uni-frankfurt.de\/en\/english\/made-to-measure-silicon-building-blocks\/\" \/>\n<meta property=\"og:locale\" content=\"en_GB\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Made-to-measure silicon building blocks | Aktuelles aus der Goethe-Universit\u00e4t Frankfurt\" \/>\n<meta property=\"og:description\" content=\"Range of applications for silicones on the increase thanks to modular, combinable building blocks. 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